TY - JOUR
T1 - 5-Nitroaminotetrazole as a building block for extended network structures
T2 - Syntheses and crystal structures of a number of heavy metal derivatives
AU - Semenov, Sergey N.
AU - Rogachev, Andrey Yu.
AU - Eliseeva, Svetlana V.
AU - Belousov, Yury A.
AU - Drozdov, Andrey A.
AU - Troyanov, Sergey I.
PY - 2007/10/30
Y1 - 2007/10/30
N2 - The lead, mercury, copper and silver derivatives of 5-nitroaminotetrazole (5-H(2)NATZ) were obtained by the reaction between the metal nitrate and potassium 5-nitroaminotetrazolate. The lead and mercury complexes were crystallized and characterized by single crystal X-ray diffraction. The lead complex has a polymeric structure formed by (PbO2)(n) chains and anions of 5-NATZ, where each lead atom is surrounded by ten oxygen atoms. The mercury salt is constructed from neutral (Hg-NATZ)(n) chains, where the mercury atom has a linear coordination. The influence of chemical hardness and charge distribution on the reactivity and coordination properties of 5-NATZ was estimated based on density functional calculations. The thermal stability of the salts was also studied. (C) 2007 Elsevier Ltd. All rights reserved.
AB - The lead, mercury, copper and silver derivatives of 5-nitroaminotetrazole (5-H(2)NATZ) were obtained by the reaction between the metal nitrate and potassium 5-nitroaminotetrazolate. The lead and mercury complexes were crystallized and characterized by single crystal X-ray diffraction. The lead complex has a polymeric structure formed by (PbO2)(n) chains and anions of 5-NATZ, where each lead atom is surrounded by ten oxygen atoms. The mercury salt is constructed from neutral (Hg-NATZ)(n) chains, where the mercury atom has a linear coordination. The influence of chemical hardness and charge distribution on the reactivity and coordination properties of 5-NATZ was estimated based on density functional calculations. The thermal stability of the salts was also studied. (C) 2007 Elsevier Ltd. All rights reserved.
U2 - 10.1016/j.poly.2007.06.035
DO - 10.1016/j.poly.2007.06.035
M3 - Article
SN - 0277-5387
VL - 26
SP - 4899
EP - 4907
JO - Polyhedron
JF - Polyhedron
IS - 17
ER -