A New Highly Selective Method for the Catalytic Epoxidation of Chiral Allylic Alcohols by Sandwich-Type Polyoxometalates with Hydrogen Peroxide

Waldemar Adam; Paul L Alsters; Ronny Neumann; Chantu R Saha-Möller; Dorit Sloboda-Rozner; R Zhang

doi:10.1055/s-2002-35570

A New Highly Selective Method for the Catalytic Epoxidation of Chiral Allylic Alcohols by Sandwich-Type Polyoxometalates with Hydrogen Peroxide

Waldemar Adam^*, Paul L Alsters, Ronny Neumann, Chantu R Saha-Möller, Dorit Sloboda-Rozner, R Zhang

^*Corresponding author for this work

Research output: Contribution to journal › Letter › peer-review

38 Citations (Scopus)

Abstract

Oxidatively and solvolytically persistent sandwich-type polyoxometalates, namely [WZnM2(ZnW9O34)(2)](q-) [M = Mn(II), Ru(III), Fe(Ill), Zn(II)], catalyze chemoselectively, diastereoselectively and regioselectively the epoxidation of chiral allylic alcohols with 30% hydrogen peroxide through a tungsten peroxo species, in which the allylic alcohol is coordinated as alcoholate (template effect).

Original language	English
Pages (from-to)	2011-2014
Number of pages	4
Journal	Synlett
Issue number	12
DOIs	https://doi.org/10.1055/s-2002-35570
Publication status	Published - 2002

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-2002-35570

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@article{518d5e3151bc4a57badd81b7bbc67a9f,

title = "A New Highly Selective Method for the Catalytic Epoxidation of Chiral Allylic Alcohols by Sandwich-Type Polyoxometalates with Hydrogen Peroxide",

abstract = "Oxidatively and solvolytically persistent sandwich-type polyoxometalates, namely [WZnM2(ZnW9O34)(2)](q-) [M = Mn(II), Ru(III), Fe(Ill), Zn(II)], catalyze chemoselectively, diastereoselectively and regioselectively the epoxidation of chiral allylic alcohols with 30\% hydrogen peroxide through a tungsten peroxo species, in which the allylic alcohol is coordinated as alcoholate (template effect). ",

author = "Waldemar Adam and Alsters, \{Paul L\} and Ronny Neumann and Saha-M{\"o}ller, \{Chantu R\} and Dorit Sloboda-Rozner and R Zhang",

year = "2002",

doi = "10.1055/s-2002-35570",

language = "English",

pages = "2011--2014",

journal = "Synlett",

issn = "0936-5214",

publisher = "Thieme",

number = "12",

}

TY - JOUR

T1 - A New Highly Selective Method for the Catalytic Epoxidation of Chiral Allylic Alcohols by Sandwich-Type Polyoxometalates with Hydrogen Peroxide

AU - Adam, Waldemar

AU - Alsters, Paul L

AU - Neumann, Ronny

AU - Saha-Möller, Chantu R

AU - Sloboda-Rozner, Dorit

AU - Zhang, R

PY - 2002

Y1 - 2002

N2 - Oxidatively and solvolytically persistent sandwich-type polyoxometalates, namely [WZnM2(ZnW9O34)(2)](q-) [M = Mn(II), Ru(III), Fe(Ill), Zn(II)], catalyze chemoselectively, diastereoselectively and regioselectively the epoxidation of chiral allylic alcohols with 30% hydrogen peroxide through a tungsten peroxo species, in which the allylic alcohol is coordinated as alcoholate (template effect).

AB - Oxidatively and solvolytically persistent sandwich-type polyoxometalates, namely [WZnM2(ZnW9O34)(2)](q-) [M = Mn(II), Ru(III), Fe(Ill), Zn(II)], catalyze chemoselectively, diastereoselectively and regioselectively the epoxidation of chiral allylic alcohols with 30% hydrogen peroxide through a tungsten peroxo species, in which the allylic alcohol is coordinated as alcoholate (template effect).

UR - https://www.scopus.com/pages/publications/0036454148

U2 - 10.1055/s-2002-35570

DO - 10.1055/s-2002-35570

M3 - Letter

SN - 0936-5214

SP - 2011

EP - 2014

JO - Synlett

JF - Synlett

IS - 12

ER -

A New Highly Selective Method for the Catalytic Epoxidation of Chiral Allylic Alcohols by Sandwich-Type Polyoxometalates with Hydrogen Peroxide

Abstract

All Science Journal Classification (ASJC) codes

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