An Iron-Capped Metal-Organic Polyyne: {[Fe](C C)(2)[W] CC CC [W](C C)(2)[Fe]}

Sergey N. Semenov, Shiva F. Taghipourian, Olivier Blacque, Thomas Fox, Koushik Venkatesan, Heinz Berke*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

The organometallic conjugated complex H(C C)(2)[W] CC CC [W](C C)(2)H {[W] = W(dppe)(2); dppe = 1,2-bis(diphenylphosphino)ethane} containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.

Original languageEnglish
Pages (from-to)7584-+
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number22
DOIs
Publication statusPublished - 9 Jun 2010

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