Abstract
The organometallic conjugated complex H(C C)(2)[W] CC CC [W](C C)(2)H {[W] = W(dppe)(2); dppe = 1,2-bis(diphenylphosphino)ethane} containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.
Original language | English |
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Pages (from-to) | 7584-+ |
Number of pages | 3 |
Journal | Journal of the American Chemical Society |
Volume | 132 |
Issue number | 22 |
DOIs | |
Publication status | Published - 9 Jun 2010 |