Catalytic system for heck reactions involving insertion into Pd-(perfluoro-organyl) bonds

Ana C. Albeniz; Pablo Espinet; Blanca Martin-Ruiz; David Milstein

doi:10.1021/ja016315b

Catalytic system for heck reactions involving insertion into Pd-(perfluoro-organyl) bonds

Ana C. Albeniz, Pablo Espinet^*, Blanca Martin-Ruiz, David Milstein^*

^*Corresponding author for this work

Research output: Contribution to journal › Letter › peer-review

69 Citations (Scopus)

Abstract

σ-Bonds between transition metals and perfluorinated groups (M−Rf) are among the strongest M−C bonds. Very few stoichiometric and, as far as we know, no catalytic reactions based on insertion of unsaturated molecules into M−Rf bonds have been reported. Alkene insertion into M−C bonds plays a key role in important catalytic processes such as alkene oligomerization, polymerization, and the Heck reaction. Such catalysis involving M−Rf bonds is desirable for the functionalization of perfluorinated compounds, important for the fine chemical and pharmaceutical industries.

Original language	English
Pages (from-to)	11504-11505
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	123
Issue number	46
DOIs	https://doi.org/10.1021/ja016315b
Publication status	Published - 21 Nov 2001

Funding

Support from the MCyT (MAT2000-1677) and the JCyL (VA80/99; VA17/00B), and a MEC fellowship to B.M-R. are acknowledged. IBERDROLA funded a stay of D.M. in Valladolid.

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja016315b

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title = "Catalytic system for heck reactions involving insertion into Pd-(perfluoro-organyl) bonds",

abstract = "σ-Bonds between transition metals and perfluorinated groups (M−Rf) are among the strongest M−C bonds. Very few stoichiometric and, as far as we know, no catalytic reactions based on insertion of unsaturated molecules into M−Rf bonds have been reported. Alkene insertion into M−C bonds plays a key role in important catalytic processes such as alkene oligomerization, polymerization, and the Heck reaction. Such catalysis involving M−Rf bonds is desirable for the functionalization of perfluorinated compounds, important for the fine chemical and pharmaceutical industries.",

author = "Albeniz, \{Ana C.\} and Pablo Espinet and Blanca Martin-Ruiz and David Milstein",

year = "2001",

month = nov,

day = "21",

doi = "10.1021/ja016315b",

language = "English",

volume = "123",

pages = "11504--11505",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Catalytic system for heck reactions involving insertion into Pd-(perfluoro-organyl) bonds

AU - Albeniz, Ana C.

AU - Espinet, Pablo

AU - Martin-Ruiz, Blanca

AU - Milstein, David

PY - 2001/11/21

Y1 - 2001/11/21

N2 - σ-Bonds between transition metals and perfluorinated groups (M−Rf) are among the strongest M−C bonds. Very few stoichiometric and, as far as we know, no catalytic reactions based on insertion of unsaturated molecules into M−Rf bonds have been reported. Alkene insertion into M−C bonds plays a key role in important catalytic processes such as alkene oligomerization, polymerization, and the Heck reaction. Such catalysis involving M−Rf bonds is desirable for the functionalization of perfluorinated compounds, important for the fine chemical and pharmaceutical industries.

AB - σ-Bonds between transition metals and perfluorinated groups (M−Rf) are among the strongest M−C bonds. Very few stoichiometric and, as far as we know, no catalytic reactions based on insertion of unsaturated molecules into M−Rf bonds have been reported. Alkene insertion into M−C bonds plays a key role in important catalytic processes such as alkene oligomerization, polymerization, and the Heck reaction. Such catalysis involving M−Rf bonds is desirable for the functionalization of perfluorinated compounds, important for the fine chemical and pharmaceutical industries.

UR - https://www.scopus.com/pages/publications/0035930041

U2 - 10.1021/ja016315b

DO - 10.1021/ja016315b

M3 - Letter

SN - 0002-7863

VL - 123

SP - 11504

EP - 11505

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 46

ER -

Catalytic system for heck reactions involving insertion into Pd-(perfluoro-organyl) bonds

Abstract

Funding

All Science Journal Classification (ASJC) codes

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