Nanocrystal Assemblies: Current Advances and Open Problems

Carlos L. Bassani; Greg van Anders; Uri Banin; Dmitry Baranov; Qian Chen; Marjolein Dijkstra; Michael S. Dimitriyev; Efi Efrati; Jordi Faraudo; Oleg Gang; Nicola Gaston; Ramin Golestanian; G. Ivan Guerrero-Garcia; Michael Gruenwald; Amir Haji-Akbari; Maria Ibáñez; Matthias Karg; Tobias Kraus; Byeongdu Lee; Reid C. Van Lehn; Robert J. Macfarlane; Bortolo M. Mognetti; Arash Nikoubashman; Saeed Osat; Oleg V. Prezhdo; Grant M. Rotskoff; Leonor Saiz; An Chang Shi; Sara Skrabalak; Ivan I. Smalyukh; Mario Tagliazucchi; Dmitri V. Talapin; Alexei V. Tkachenko; Sergei Tretiak; David Vaknin; Asaph Widmer-Cooper; Gerard C.L. Wong; Xingchen Ye; Shan Zhou; Eran Rabani; Michael Engel; Alex Travesset

doi:10.1021/acsnano.3c10201

Nanocrystal Assemblies: Current Advances and Open Problems

Carlos L. Bassani, Greg van Anders, Uri Banin, Dmitry Baranov, Qian Chen, Marjolein Dijkstra, Michael S. Dimitriyev, Efi Efrati, Jordi Faraudo, Oleg Gang, Nicola Gaston, Ramin Golestanian, G. Ivan Guerrero-Garcia, Michael Gruenwald, Amir Haji-Akbari, Maria Ibáñez, Matthias Karg, Tobias Kraus, Byeongdu Lee, Reid C. Van LehnRobert J. Macfarlane, Bortolo M. Mognetti, Arash Nikoubashman, Saeed Osat, Oleg V. Prezhdo, Grant M. Rotskoff, Leonor Saiz, An Chang Shi, Sara Skrabalak, Ivan I. Smalyukh, Mario Tagliazucchi, Dmitri V. Talapin, Alexei V. Tkachenko, Sergei Tretiak, David Vaknin, Asaph Widmer-Cooper, Gerard C.L. Wong, Xingchen Ye, Shan Zhou, Eran Rabani, Michael Engel, Alex Travesset^*

^*Corresponding author for this work

Department of Physics of Complex Systems

Research output: Contribution to journal › Review article › peer-review

62 Citations (Scopus)

Abstract

We explore the potential of nanocrystals (a term used equivalently to nanoparticles) as building blocks for nanomaterials, and the current advances and open challenges for fundamental science developments and applications. Nanocrystal assemblies are inherently multiscale, and the generation of revolutionary material properties requires a precise understanding of the relationship between structure and function, the former being determined by classical effects and the latter often by quantum effects. With an emphasis on theory and computation, we discuss challenges that hamper current assembly strategies and to what extent nanocrystal assemblies represent thermodynamic equilibrium or kinetically trapped metastable states. We also examine dynamic effects and optimization of assembly protocols. Finally, we discuss promising material functions and examples of their realization with nanocrystal assemblies.

Original language	English
Pages (from-to)	14791-14840
Number of pages	50
Journal	ACS Nano
Volume	18
Issue number	23
DOIs	https://doi.org/10.1021/acsnano.3c10201
Publication status	Published Online - 30 May 2024

Funding

This research was supported in part by the National Science Foundation under Grant No. NSF PHY-1748958 to the Kavli Institute for Theoretical Physics. The biophysics part of this paper was supported in part by the Gordon and Betty Moore Foundation Grant No. 2919.02. CLB acknowledges the sponsorship of the Alexander von Humboldt Foundation through the Humboldt Research Fellowship for postdoctoral researchers, and the support of the Emerging Talents Initiative (ETI) and the EAM Starting Grant (EAM-SG23-1) of the Competence Center Engineering of Advanced Materials of the Friedrich-Alexander-Universität Erlangen-Nürnberg. CLB and ME acknowledge the support of the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) Project-ID 416229255-SFB 1411. The research of AT was supported by the U.S. Department of Energy (U.S. DOE), Office of Basic Energy Sciences, Division of Materials Sciences and Engineering. Iowa State University operates Ames National Laboratory for the U.S. DOE under Contract DE-AC02-07CH11358. Publisher Copyright: © 2024 American Chemical Society.

All Science Journal Classification (ASJC) codes

General Materials Science
General Engineering
General Physics and Astronomy

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10.1021/acsnano.3c10201

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Bassani, C. L., van Anders, G., Banin, U., Baranov, D., Chen, Q., Dijkstra, M., Dimitriyev, M. S., Efrati, E., Faraudo, J., Gang, O., Gaston, N., Golestanian, R., Guerrero-Garcia, G. I., Gruenwald, M., Haji-Akbari, A., Ibáñez, M., Karg, M., Kraus, T., Lee, B., ... Travesset, A. (2024). Nanocrystal Assemblies: Current Advances and Open Problems. ACS Nano, 18(23), 14791-14840. Advance online publication. https://doi.org/10.1021/acsnano.3c10201

@article{24e631cfa98c4e41986a846f0cc787d9,

title = "Nanocrystal Assemblies: Current Advances and Open Problems",

abstract = "We explore the potential of nanocrystals (a term used equivalently to nanoparticles) as building blocks for nanomaterials, and the current advances and open challenges for fundamental science developments and applications. Nanocrystal assemblies are inherently multiscale, and the generation of revolutionary material properties requires a precise understanding of the relationship between structure and function, the former being determined by classical effects and the latter often by quantum effects. With an emphasis on theory and computation, we discuss challenges that hamper current assembly strategies and to what extent nanocrystal assemblies represent thermodynamic equilibrium or kinetically trapped metastable states. We also examine dynamic effects and optimization of assembly protocols. Finally, we discuss promising material functions and examples of their realization with nanocrystal assemblies.",

author = "Bassani, \{Carlos L.\} and \{van Anders\}, Greg and Uri Banin and Dmitry Baranov and Qian Chen and Marjolein Dijkstra and Dimitriyev, \{Michael S.\} and Efi Efrati and Jordi Faraudo and Oleg Gang and Nicola Gaston and Ramin Golestanian and Guerrero-Garcia, \{G. Ivan\} and Michael Gruenwald and Amir Haji-Akbari and Maria Ib{\'a}{\~n}ez and Matthias Karg and Tobias Kraus and Byeongdu Lee and \{Van Lehn\}, \{Reid C.\} and Macfarlane, \{Robert J.\} and Mognetti, \{Bortolo M.\} and Arash Nikoubashman and Saeed Osat and Prezhdo, \{Oleg V.\} and Rotskoff, \{Grant M.\} and Leonor Saiz and Shi, \{An Chang\} and Sara Skrabalak and Smalyukh, \{Ivan I.\} and Mario Tagliazucchi and Talapin, \{Dmitri V.\} and Tkachenko, \{Alexei V.\} and Sergei Tretiak and David Vaknin and Asaph Widmer-Cooper and Wong, \{Gerard C.L.\} and Xingchen Ye and Shan Zhou and Eran Rabani and Michael Engel and Alex Travesset",

year = "2024",

month = may,

day = "30",

doi = "10.1021/acsnano.3c10201",

language = "English",

volume = "18",

pages = "14791--14840",

journal = "ACS Nano",

issn = "1936-0851",

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Bassani, CL, van Anders, G, Banin, U, Baranov, D, Chen, Q, Dijkstra, M, Dimitriyev, MS, Efrati, E, Faraudo, J, Gang, O, Gaston, N, Golestanian, R, Guerrero-Garcia, GI, Gruenwald, M, Haji-Akbari, A, Ibáñez, M, Karg, M, Kraus, T, Lee, B, Van Lehn, RC, Macfarlane, RJ, Mognetti, BM, Nikoubashman, A, Osat, S, Prezhdo, OV, Rotskoff, GM, Saiz, L, Shi, AC, Skrabalak, S, Smalyukh, II, Tagliazucchi, M, Talapin, DV, Tkachenko, AV, Tretiak, S, Vaknin, D, Widmer-Cooper, A, Wong, GCL, Ye, X, Zhou, S, Rabani, E, Engel, M & Travesset, A 2024, 'Nanocrystal Assemblies: Current Advances and Open Problems', ACS Nano, vol. 18, no. 23, pp. 14791-14840. https://doi.org/10.1021/acsnano.3c10201

TY - JOUR

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AU - Bassani, Carlos L.

AU - van Anders, Greg

AU - Banin, Uri

AU - Baranov, Dmitry

AU - Chen, Qian

AU - Dijkstra, Marjolein

AU - Dimitriyev, Michael S.

AU - Efrati, Efi

AU - Faraudo, Jordi

AU - Gang, Oleg

AU - Gaston, Nicola

AU - Golestanian, Ramin

AU - Guerrero-Garcia, G. Ivan

AU - Gruenwald, Michael

AU - Haji-Akbari, Amir

AU - Ibáñez, Maria

AU - Karg, Matthias

AU - Kraus, Tobias

AU - Lee, Byeongdu

AU - Van Lehn, Reid C.

AU - Macfarlane, Robert J.

AU - Mognetti, Bortolo M.

AU - Nikoubashman, Arash

AU - Osat, Saeed

AU - Prezhdo, Oleg V.

AU - Rotskoff, Grant M.

AU - Saiz, Leonor

AU - Shi, An Chang

AU - Skrabalak, Sara

AU - Smalyukh, Ivan I.

AU - Tagliazucchi, Mario

AU - Talapin, Dmitri V.

AU - Tkachenko, Alexei V.

AU - Tretiak, Sergei

AU - Vaknin, David

AU - Widmer-Cooper, Asaph

AU - Wong, Gerard C.L.

AU - Ye, Xingchen

AU - Zhou, Shan

AU - Rabani, Eran

AU - Engel, Michael

AU - Travesset, Alex

PY - 2024/5/30

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AB - We explore the potential of nanocrystals (a term used equivalently to nanoparticles) as building blocks for nanomaterials, and the current advances and open challenges for fundamental science developments and applications. Nanocrystal assemblies are inherently multiscale, and the generation of revolutionary material properties requires a precise understanding of the relationship between structure and function, the former being determined by classical effects and the latter often by quantum effects. With an emphasis on theory and computation, we discuss challenges that hamper current assembly strategies and to what extent nanocrystal assemblies represent thermodynamic equilibrium or kinetically trapped metastable states. We also examine dynamic effects and optimization of assembly protocols. Finally, we discuss promising material functions and examples of their realization with nanocrystal assemblies.

UR - https://www.scopus.com/pages/publications/85195093044

U2 - 10.1021/acsnano.3c10201

DO - 10.1021/acsnano.3c10201

M3 - Review article

AN - SCOPUS:85195093044

SN - 1936-0851

VL - 18

SP - 14791

EP - 14840

JO - ACS Nano

JF - ACS Nano

IS - 23

ER -

Nanocrystal Assemblies: Current Advances and Open Problems

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